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Electrochemical
Chloride
Extraction
The Need
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Conventional
methods to deal with chloride-contaminated concrete require
the removal of the contaminated concrete and replacement with
uncontaminated concrete.
These methods are noisy, dirty, time consuming, costly,
and in some cases structurally detrimental.
The Norcure system is a rehabilitation method developed
to remove salt (chloride ions) from salt contaminated concrete
structures without damaging the concrete.
The removal of chloride ions stops the corrosion of
embedded reinforcing steel and greatly extends the service
life of salt contaminated structures.
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The Technology
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The removal of
chloride ions and the re-establishment of the passive oxide
layer around the reinforcing steel eliminates or greatly
reduces on-going rebar corrosion.
Chloride ions can be drawn out of the concrete by
applying a direct current electric field between a temporary
anode at the surface of the concrete and the reinforcing steel
(cathode) within the concrete.
Chloride ions carry a net negative charge, and thus
migrate from areas near the reinforcing steel toward the
surface mounted anode, and out of the concrete. Simultaneously, hydroxyl ions are produced around the rebar
within the concrete. The
hydroxyl restores a highly alkaline environment around the
rebar, further suppressing corrosion of the steel.
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The Benefits
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The Norcure
process is a quiet, clean and nondestructive method. The
process takes about four to eight weeks to reduce the chloride
ions in the vicinity of the reinforcing steel to levels
required to prevent corrosion. The
combined effects of removing chloride ions and restoring an
alkaline environment around the steel provide a long life for
the structure, free from corrosion.
A
sister technology is also being used to re-alkalize concrete
damaged through carbonation.
Experimental work is underway examining the application
of lithium-based electrolytes for their ability to mitigate
damage caused by alkali-silica reactive aggregate in concrete. |
Status
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Trial
demonstration projects using the Norcure system began in 1989.
The first trial project in North America was for the Ontario
Ministry of Transportation on a portion of the substructure of
the Burlington
Skyway. This project was completed as part of the
Strategic Highway Research Program (SHRP) which is a jointly
funded program of the U.S. and Canada. The first full-scale
commercial project in North America was completed n 1994 on a
bridge substructure for Saskatchewan
Highways and Transportation. The project included the
treatment of 24 salt contaminated columns.
In
recent years projects have been undertaken throughout many
parts of North America, Europe, and Australia; as well as
parts of Asia and the Middle East. Acceptance of the system
seems to be growing rapidly now that the long-term results of
the early SHRP test projects are available. The Federal
Highway Administration is actively promoting the use of this
technology to state DOT's because it presents a viable option
for extending the life of existing structures, and saving
money in the process. About 5,000,000
sq. ft. of concrete has been treated to date. |
Barriers
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1.
Epoxy
coated reinforcing steel – insulates the reinforcing steel
preventing electrical continuity, and effective chloride
removal.
2.
Pre-stressed or post-tensioned steel – potential risk
of creating hydrogen embrittlement in the reinforcing steel
through application of a voltage as used in a chloride
extraction or cathodic protection system.
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Points of Contact
- Chris
Ball; Vector Corrosion Technologies, Medina, Ohio, 330-72301177,
chrisb@vectorgroup.com
- Daniel
Burns, Vector Corrosion Technologies, Fargo, North Dakota,
701-280-9697, danb@vectorgroup.com
- Sean
Abbott; Vector Corrosion Technologies, Winnipeg, Manitoba,
Canada, 204-489-6300, seana@vectorgroup.com
References
- Norcure Chloride
Removal System, Inc. <http://www.norcure.com/>
- Nova News Release
1996
Disclaimer Statement
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Neither the Construction
Industry Institute nor Purdue University in any way endorses this
technology or represents
that the information presented can be relied upon without further investigation. |
JK07
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